The preparation of polyfluoroalkyl phosphonitrilates and N-(perfluoracyl) phosphoramidic dichlorides

Journal of Inorganic and Nuclear Chemistry(1962)

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Abstract
The phosphonitrilic fluorides can be made to react readily with sodium polyfluoroalkyl alcoholates, CHF2(CF2)nCH2ONa, to give high yields of the corresponding phosphonitrilic esters, viscous, high boiling liquids, which are soluble in a variety of organic and fluorocarbon solvents, but insoluble in water.
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polyfluoroalkyl phosphonitrilates
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