Palladocarbosilane dendrimers as catalysts for the asymmetric hydrovinylation of styrene in supercritical carbon dioxide
Journal of Organometallic Chemistry(2008)
摘要
P-Stereogenic phosphine-containing carbosilane dendrimers with PdCl(η3-2-MeC3H4) units grafted on the periphery have been tested in the asymmetric hydrovinylation of styrene in scCO2 media.
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关键词
Dendrimer,Palladium,Asymmetric hydrovinylation,Supercritical carbon dioxide
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