Iron(III) tosylate-catalyzed deprotection of aromatic acetals in water

Margaret E. Olson,James P. Carolan,Michael V. Chiodo,Phillip R. Lazzara,Ram S. Mohan

Tetrahedron Letters（2010）

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摘要

The deprotection of aromatic as well as conjugated acetals and ketals in water is catalyzed by iron(III) tosylate (1.0–5.0mol%). Iron(III) tosylate is an inexpensive and readily available catalyst. The use of water, the most environmentally benign solvent, makes this procedure especially attractive for acetal deprotection.

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关键词

Deprotection,Acetals,Iron(III) tosylate,Water

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