Multiphase telomerisation of butadiene with acetic acid and acetic anhydride

Journal of Organometallic Chemistry(2008)

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Abstract
Two different routes to acetoxyoctadiene are presented. The first one uses the well-known telomerisation of butadiene with acetic acid operating in a multiphase semi-batch mode. The second reaction involves the cleavage of acetic anhydride, hydrogen transfer via ketene formation and thus a telomerisation as well.
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Key words
Telomerisation,Acetic anhydride,Ketene,Extended Keim-mechanism,Multiphase semi-batch mode
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