A stereoselective synthesis of squalamine
Tetrahedron（2002）
摘要
Squalamine (1) was synthesized stereoselectively in 14 steps and 19% overall yield from 3-keto-5α-chenodeoxycholanate (2) by using a modified Sharpless asymmetric dihydroxylation as the key step.
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关键词
squalamine,improved Sharpless AD,aminosterol,stereoselective
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