Ligand field parameters of Mo(III) complexes
MOLECULAR PHYSICS(2006)
Abstract
Spectral absorption data of some octahedral chromophores of Mo3+ are reported, together with values of Δ and β 55 parameters, whenever experimentally attainable. For complexes with sufficiently electronegative ligands, almost complete ligand field spectra can be observed, whereas in other complexes intense charge transfer bands occur; with ligands of low electronegativity, charge transfer bands from the central ion to the ligands are frequently encountered.
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Key words
charge transfer
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