Photochromic properties of phenanthroline-annulated spirooxazine in the solid state
Russian Chemical Bulletin(2011)
摘要
Photochromic transformations of phenanthroline-annulated spirooxazine were observed in polycrystalline powders and solid-phase films obtained from solutions by solvent evaporation. The spectral and kinetic properties of the solid-phase films were studied by stationary absorption spectroscopy and laser flash photolysis. The mechanism of photoinitiated reactions of solid-phase samples of phenanthroline-annulated spirooxazine includes mutual transformations of different transoid isomers of the merocyanine form.
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关键词
photochemistry,photochromism,laser flash photolysis,spectrophotometry
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