Synthesis of a 10-membered ring with eleutheside functionality by Nozaki–Hiyama–Kishi coupling
Tetrahedron(2007)
摘要
The synthesis of a medium-sized unit of 15-seco-eleutheside analogue 3 has been achieved by the NiCl2/CrCl2-mediated intramolecular coupling of iodoaldehyde 8 with excellent yields. An important issue in our reported route to 3 involved a pyranose/furanose rearrangement, which opened the tetrahydrofuran ring on to the target.
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关键词
Eleuthesides,Eleutherobin,Nozaki–Hiyama–Kishi
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