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一维铜配位聚合物的合成与磁性研究

WANG Li-jun,SHI Li-ping,LIU Chun

Journal of Northeast Normal University（2006）

Cited 6|Views1
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Abstract
利用水热方法以邻吡啶羧酸乙酯和氯化铜为原料,原位合成了一维的配位聚合物[Cu(pc)2.2H2O]n(pc=2-羧酸吡啶).该配合物的Cu2+与两个pc直接配位形成重复单元Cu(pc)2,通过相邻单元间羧基氧形成八面体配位并组成了一维的链状结构.磁性表征显示链内邻近的Cu2+之间存在弱的铁磁耦合作用.
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Key words
hydrothermal synthesis,crystal structure,ferromagnetic coupling
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