Direct Generation of Thiomethylmanganese Reagents and Their Reactions with Electrophiles1
ORGANOMETALLICS(2000)
摘要
Trialkylmanganese(II) ate reagents, "R3MnLi", reacted with iodomethyl sulfides to produce thiomethylmanganese reagents, where the manganate serves as a reductant, not an alkylation agent. In this reductive metalation of halides with alkylmanganese ate complexes, the relationship between oxidative addition and the metal-halogen exchange reaction was revealed. A wide variety of modifications of "thiomethylmanganese reagents" thus generated in reactivity could be made.
更多查看译文
关键词
thiomethylmanganese reagents,electrophiles<sup>1</sup>,reactions
AI 理解论文
溯源树
样例
![](https://originalfileserver.aminer.cn/sys/aminer/pubs/mrt_preview.jpeg)
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要