Preparation and Structure of syn- and anti-Bis(μ-thioacetato-κ2S)bis[bis(dithioacetato-κS:κS′)iridium(III)]

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN(2005)

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摘要
Iridium(III) dinuclear complexes with thioacetato bridges and dithioacetato chelates were prepared by the reaction of H(2)IrCl(6)(.)6H(2)O with a mixture of Li2CO3, MeCOSH, MeCO2H, and (MeCO)(2)O under O-2. X-ray structures of two geometrical isomers for [{Ir(S2CMe)(2)}(2)(mu-SOCMe)(2)] were determined.
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