Br3In · NH2Si(CH3)3 - ein stabiles Addukt des instabilen Trimethylsilylamins

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE(1998)

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摘要
Heating a solution of indium tribromide in bis(trimethylsilyl)amine at about 55 degrees C for 30 to 35 hours the two adducts Br3In . NH2SiMe3 and Br3In . NH(SiMe3)(2) are formed in a 3:1 molar ratio. both compounds have been characterized by NMR, IR and Raman spectra; the X-ray structure determination of the title compound is reported.
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关键词
trimethylsilylamine,indium tribromide adduct,NMR,vibrational spectra,X-ray structure
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