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Synthesis of 5-Hydroxy-3-methyl-3-pyrrolin-2-one [(±)-Jatropham, an Antitumor Alkaloid] and Its 4-Methyl Isomer

Tatsuo Nagasaka,Sayuri Esumi,Naganori Ozawa,Yoshiyuki Kosugi,Fumiko Hamaguchi

HETEROCYCLES（1981）

Cited 23|Views2
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Abstract
Das aus Succinimid nach Speckamp zugängliche Ethoxypyrrolidinon (1) wird in das Trimethylsilylderivat (II) und weiter in den Selenoether (I11) übergeführt, der durch oxidative Eliminierung die Verbindung (V) ergibt.
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Key words
antitumor alkaloid,cheminform abstract,synthesis
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