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Reactivity of electron-poor decamethyl-1,3-diboraruthenocene with sulfur and phosphorus compounds

Journal of Organometallic Chemistry(2004)

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摘要
Decamethyl-1,3-diboraruthenocene 1 reacts with sulfur and hydrogen sulfide to give the corresponding ruthena-sulfide sandwich 3 and a ruthenathiacarboranyl complex, respectively. 3 loses sulfur and unexpectedly a closo-diruthenacarborane is formed. COS and CS2 are incorporated into 1 to yield dinuclear ruthenium compounds 7 (see pictogram) and 8. On heating 1 and P4 in toluene, a sandwich is obtained by formal insertion of a PH group into the diborolyl ring of 1.
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关键词
Ruthenium,Sandwich complexes,Diboroles,Sulfur,Phosphorus
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