Synthesis and structural characterization of the anionic chelates of hypercoordinate silicon, the derivatives of glycolic and tartaric acids

Aleksandr G. Shipov,Alexander A. Korlyukov,Dmitry E. Arkhipov,Evgeniya P. Kramarova,Vadim V. Negrebetskii,Sergey Yu. Bylikin,Alexey A. Nikolin,Huntse Fan,Mikhail Yu. Antipin,Yuri I. Baukov

Mendeleev Communications（2010）

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摘要

Reactions of 1-(trimethoxysilylmethyl)-2-piperidone with glycolic and ( R , R )-tartaric acids in the presence of dicyclohexylamine afford cation–anionic complexes with different coordination states of the Si atoms.

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关键词

hypercoordinate silicon,anionic chelates,tartaric acids

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