Stereoselective reductions of N-Boc-hexahydro-1H-indolin-5(6H)-ones

Michael A. Brodney,Marcus L. Cole,Jamie A. Freemont,Stella Kyi,Peter C. Junk,Albert Padwa,Andrew G. Riches,John H. Ryan

Tetrahedron Letters（2007）

引用 12|浏览11

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摘要

We report the divergent effects of a 3a-methyl and 3a-phenyl substituent on the chemoselectivity and stereoselectivity of reduction of the enamide moiety of N-Boc-tetrahydro-1H-indolin-5(6H)-ones.

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关键词

Hydroindole,Intramolecular Diels–Alder cyclization,Furan,Stereoselective,Enamide reduction

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