Synthesis of 7-Chloro- and 7-Hydroxybicyclo[5.2.2]undeca-1(9),10-dienes

Yoshito Tobe,Kiyomi Kakiuchi,Kazuya Kobiro,Yoshinobu Odaira

Synthesis-stuttgart（1993）

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摘要

7-Chlorobicyclo[5.2.2]undeca-1(9),10-diene (2a) and the 7-hydroxy derivative 2b were prepared by oxidative decarboxylation of tricyclo[5.2.2.0 1,7 ]undec-10-ene-8-carboxylic acids 6a and 6b followed by acid-catalyzed isomerization

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