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Conductivity of K (11)[Sm(AlW (11)O 39H 2 ) 2 ]·21H 2 O Treated by Chemistry-Heated Diffusion of Mixed Rare Earth Ce and La Permeation

稀土学报(英文版)(2005)

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Abstract
The title compound was prepared and treated by high temperature gaseous mix rare earth permeation. ICP, IR, TG-DTA, XPS, XRD were used to characterize the title compound and the treated sample. The results confirm that Ce and La can be permeated into the body of the title compound. Four-probe method was used to measure the conductivities. A novel result that the conductivity of the permeated compound (δ=9.2×10 -3 S·cm -1)improved by 7.1×106 times than that of the title compound(δ=1.29×10 -9 S·cm -1) is received.
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Key words
permeation,conductivity,rare earths,four-probe,POMs
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