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Oxidation of indolines to nitrones and new rearrangement in seco-curane type indoline alkaloids

François Trigalo,Marie-Thérèse Martin,Benoı̂t Rasolondratovo,Alain Blond,Jean Jacques Youte,Philippe Rasoanaivo,François Frappier

Tetrahedron（2002）

Cited 3|Views4
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Abstract
At room temperature 3-chloroperoxybenzoic acid oxidizes the deacetylated strychnobrasiline to the corresponding nitrone. Two unexpected rearrangements are observed when the reaction is performed at 40°C.
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alkaloid,Baeyer–Villiger reaction,indoline,nitrone,15N NMR
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