Oxidation of indolines to nitrones and new rearrangement in seco-curane type indoline alkaloids

François Trigalo,Marie-Thérèse Martin,Benoı̂t Rasolondratovo,Alain Blond,Jean Jacques Youte,Philippe Rasoanaivo,François Frappier

Tetrahedron（2002）

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摘要

At room temperature 3-chloroperoxybenzoic acid oxidizes the deacetylated strychnobrasiline to the corresponding nitrone. Two unexpected rearrangements are observed when the reaction is performed at 40°C.

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关键词

alkaloid,Baeyer–Villiger reaction,indoline,nitrone,15N NMR

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