Turning dihydrogen gas into a strong acid. Formation and reactions of the very acidic ruthenium dihydrogen complexes trans-[Ru(H2)(CNH){PPh2(CH2)nPPh2}2][O3SCF3]2 (n = 2 or 3)
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS（1998）
Abstract
New, very acidic ruthenium dihydrogen complexes containing the hydrogen isocyanide ligand have been synthesised; when formed under 1 atm H-2 they have been shown to spontaneously eliminate trifluoromethylsulfonic acid.
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Key words
dihydrogen gas,trans-ruh2cnh{pph2ch2npph2}2o3scf32,reactions,ruthenium,strong acid,trans-[ru
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