Suzuki-Miyaura cross-coupling reaction catalyzed by a highly stable Pd(P-Phos)Cl2 complex at room temperature under air
Chinese Journal of Catalysis(2013)
摘要
A new Pd(P-Phos)Cl2 complex was synthesized and characterized by 1H NMR, 13C NMR, 31P NMR, and X-ray single crystal structure determination. The complex proved to be a highly stable and efficient catalyst for substrates with a wide range of functional groups in Suzuki-Miyaura cross-coupling reactions under air at room temperature. Low catalyst loadings were employed and turnover number of up to 49000 was obtained.
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关键词
Palladium complex,P-Phos,Suzuki-Miyaura cross-coupling reaction,Room temperature,Air
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