C60衍生物的合成及在水性成膜材料中的抗近红外和紫外性能
Polymer Materials Science & Engineering（2006）
Abstract
采用无皂乳液,自由基聚合的方法,分别制备了水溶性富勒烯衍生物C60/丙烯酸/丙烯酸丁酯(C60/AA/BA)无皂乳液和C60/聚-2-丙烯酰胺-甲基丙磺酸(C60/PAMPS).TEM分析表明,C60/AA/BA无皂乳液中分散着粒径约为30 nm～50 nm的成串的纳米微球,C60/PAMPS的形貌为球形分散体,平均粒径为40 nm～50 nm左右.近红外和紫外分析表明,将水溶性C60衍生物应用在隔热、透明、节能水性涂料的研制方面具有潜在的应用前景.
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Key words
water-soluble C_(60) derivative,properties of anti-near-infrared/ultraviolet,soap-free emulsion polymerization
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