Total synthesis of balanol: a potent protein kinase C inhibitor of fungal origin

C. P. Adams,S. M. Fairway,C. J. Hardy,D. E. Hibbs,M. B. Hursthouse,A. D. Morley,B. W. Sharp,N. Vicker,I. Warner

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1（1995）

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摘要

The total synthesis of the fungal metabolite balanol, a potent inhibitor of protein kinase C, is described. The synthesis includes a novel synthesis of 3-amino-4-hydroxyazepanes via a directed ring expansion of 3-bromopiperidin-4-ones.

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关键词

protein kinase c,total synthesis

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