Total synthesis of balanol: a potent protein kinase C inhibitor of fungal origin
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1(1995)
摘要
The total synthesis of the fungal metabolite balanol, a potent inhibitor of protein kinase C, is described. The synthesis includes a novel synthesis of 3-amino-4-hydroxyazepanes via a directed ring expansion of 3-bromopiperidin-4-ones.
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关键词
protein kinase c,total synthesis
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