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ChemInform Abstract: Facile Reduction of Malonate Derivatives Using NaBH4/Br2: An Efficient Route to 1,3-Diols.

Matthew Tudge,Hiroko Mashima,Cecile Savarin,Guy Humphrey,Ian Davies

Cheminform（2008）

Cited 6|Views6
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Abstract
Borane–dimethoxyethane generated from sodium borohydride–bromine mixtures efficiently reduces a wide range of malonate derivatives to the corresponding 1,3-diols. This new reagent system represents a milder alternative to current methods available, providing the requisite 1,3-diols in higher yields over shorter reaction times.
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Key words
malonate derivatives,facile reduction,nabh4/br2,nabh4/br2
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