Measurement, analysis, and modeling of fine particulate matter in eastern North Carolina.

An analysis of fine particulate data in eastern North Carolina was conducted to investigate the impact of the hog industry and its emissions of ammonia into the atmosphere. The fine particulate data are simulated using ISORROPIA, an equilibrium thermodynamic model that simulates the gas and aerosol equilibrium of inorganic atmospheric species. The observational data analyses show that the major constituents of fine particulate matter (PM,.,) are organic carbon, elemental carbon, sulfate, nitrate, and ammonium. The observed PM,., concentration is positively correlated with temperature but anticorrelated with wind speed. The correlation between PM,., and wind direction at some locations suggests an impact of ammonia emissions from hog facilities on PM,., formation. The modeled results are in good agreement with observations, with slightly better agreement at urban sites than at rural sites. The predicted total inorganic particulate matter (PM) concentrations are within 5% of the observed values under conditions with median initial total PM species concentrations, median relative humidity (RH), and median temperature. Ambient conditions with high PM precursor concentrations, low temperature, and high RH appear to favor the formation of secondary PM.