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The synthesis of chloromethyl complexes of manganese, rhenium and ruthenium and the reactions of some chloromethyl complexes with triphenylphosphine

Cheryl Botha,John R. Moss,Simon Pelling

Journal of Organometallic Chemistry（1981）

Cited 38|Views3
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Abstract
The syntheses of some new chloromethyl complexes are reported. The reactions of these and other chloromethyl complexes with triphenylphosphine have been investigated. Fe(Cp)(CO)2CH2Cl and W(Cp)(CO)3CH2Cl yield the cationic ylide complexes [Fe(Cp)(CO)2CH2PPh3]+ and [W(Cp)(CO)3CH2PPh3]+. Some new methoxymethyl complexes are also described.
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Multicomponent Reactions
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