Asymmetric Synthesis Of Salvinorin A, A Potent Kappa Opioid Receptor Agonist

Jonathan R. Scheerer,Jonathan F. Lawrence,Grace C. Wang,David A. Evans

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY（2007）

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摘要

The stereoselective synthesis of salvinorin A is described. A macrocyclic bis-Michael reaction cascade provides the requisite tricyclic skeleton as a single diastereomer.

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