SUZUKI CROSS-COUPLING REACTIONS OF NONRACEMIC VINYLBORONO-?-AMINO ACIDS

Sylvain Collet,Ren�e Danion-Bougot,Daniel Danion

SYNTHETIC COMMUNICATIONS（2001）

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摘要

Vinylborono-alpha -amino acids undergo Suzuki coupling with vinylic or aromatic halides, allowing an easy access to stereodefined unsaturated nonproteinogenic alpha -amino acids. With cesium fluoride as the base, the protective groups are not affected.

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