COMPLETE CHROMATOGRAPHIC RESOLUTION OF AXIALLY CHIRAL β-DIKETONATE COMPLEXES ON CELLULOFINE C-200 [1]

Yoshiharu Nakano,Takeshi Kawaguchi,Yuzo Yoshikawa

JOURNAL OF COORDINATION CHEMISTRY（2006）

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摘要

New chromatography on Cellulofine C-200 (modified polysaccharide ion exchanger) completely resolved the atropisomers reported previously [2]. The present technique needs no optically active eluting agents, differing from conventional chromatography on SP-Sephadex. The chromatographed atropisomers, axially chiral beta-diketonate cobalt(III)-tren complexes, are listed in the table in the text.

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关键词

axial chirality,cellulofine C-200,beta-diketonate cobalt(III)-tren complexes

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