Initial photoluminescence decay rates in amorphous phosphorus
SOLID STATE COMMUNICATIONS(1987)
摘要
Previous measurements of the photoluminescence of amorphous phosphorus have not been able to distinguish between two models of the time-dependent shift of the emission energy of the early radiative recombination. This may arise from recombination of carriers trapped at charged defects or from thermalisation of a carrier in a tail of localised states. The present work extends the time resolution of the luminescence measurement to ≈50 ps which enables a distinction to be made between the two models. The initial decay rates for luminescence in the photon energy ranges 1.45 – 1.6 and 1.45 – 1.85 eV are the same to within ≈1% at 4 K, which supports the assignment of the recombination to carriers trapped at oppositely charged intrinsic defects. The temperature dependence of the initial decay follows the empirical law ν( T ) = ν 1 + ν 0 exp( T T 0 ) with ν 1 = 8.6 × 10 8 s -1 , ν 0 = 3.7 × 10 8 s -1 and T 0 = 104 K. A temperature-dependent branching between two radiative channels is proposed in order to reconcile these observations with earlier work.
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关键词
decay rate,phosphorus
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