Synthesis of the antibiotically active part of agrocin 84

Dmitri Filippov,Cornelis M Timmers,Aaron R Roerdink,Gijs A van der Marel,Jacques H van Boom

TETRAHEDRON LETTERS（1998）

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摘要

Phosphitylation of bis-O-silylated threo-2,3-dihydroxy-4-methylpentanamide and condensation of the resulting N-acylphosphorodiamidite with 2'-O-acetyl-3'-deoxyarabinoadenosine led, after oxidation and deprotection, to the isolation of the title compound. (C) 1998 Elsevier Science Ltd. Ail rights reserved.

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agrocin,synthesis

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