Dimeric porphyrins linked by conjugated groups containing triple bonds: the crystal structure of the nickel octaethylporphyrin dimer bridged by 2,5-diethynylthiophene
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS(1994)
摘要
The conjugated bridge and the attached mese-carbons in the title dimer are almost coplanar; the porphyrin rings are ruffled and distorted in this vicinity, indicating strong interporphyrin interaction via the pi-orbitals of the diethynylthiophene unit.
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关键词
nickel,crystal structure
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