New Paracyclophane Phosphine for Highly Enantioselective Ruthenium-Catalyzed Hydrogenation of Prochiral Ketones

Murthy Cheemala,Maud Gayral,John Brown,Kai Rossen,Paul Knochel

SYNTHESIS-STUTTGART（2007）

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摘要

The synthesis of a new paracyclophane phosphine is described. This ligand was highly efficient in the ruthenium-catalyzed asymmetric hydrogenation of various aromatic and heteroaromatic ketones.

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关键词

paracyclophane,hydrogenation,ruthenium,ketones,P,P-ligands

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