Hydrogen-Production And Deuterium-Proton Exchange-Reactions Catalyzed By Desulfovibrio Nickel(Ii)-Substituted Rubredoxins

P Saint-Martin,P A Lespinat,G Fauque,Y Berlier,J Legall,I Moura,M Teixeira,A V Xavier,J J Moura

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA（1988）

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摘要

The nickel tetrahedral sulfur-coordinated core formed upon metal replacement of the native iron in Desulfovibrio sp. rubredoxins is shown to mimic the reactivity pattern of nickel-containing hydrogenases with respect to hydrogen production, deuterium-proton exchange, and inhibition by carbon monoxide.

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关键词

hydrogen production,biomedical research,carbon monoxide,iron,nickel,bioinformatics

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