Enantioselective total synthesis of (+)-sarcodictyenone

Takako Yamazaki,Minoru Ishikawa,Miki Uemura,Yuko Kanda,Hisashi Takei,Morio Asaoka

Tetrahedron（2008）

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摘要

The first enantioselective total synthesis of (+)-sarcodictyenone is described [4.3% overall yield from (5R,6R)-6-methyl-5-trimethylsily-2-cyclohexenone]. This work establishes the absolute stereochemistry of the natural product.

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关键词

(+)-Sarcodictyenone,Terpenoid,Asymmetric synthesis,Hydroxycyclohexenone

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