Vitamin B12 Catalysis of Zinc-Mediated 6-Deoxy-6-iodopyranoside Fragmentation: A Mild and Convenient Preparation of ω-Unsaturated Hexose Derivatives (5-Hexenoses)
Cheminform（2000）
Abstract
The known zinc-mediated preparation of 5-hexenoses by fragmentation of 6-iodopyranosides can be performed in a simple, fast, and mild way, with less side reactions, when vitamin B-12 is employed as a catalyst.
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Key words
fragmentation,zinc,vitamin B-12 catalysis,6-deoxy-6-iodopyranosides,5-hexenoses
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