Thermal decomposition study of bismuth (III) trichloride complex with 1,10-phenanthroline as the ligand

The complex BiCl 3 ·L (L = 1,10-phenanthroline) was synthesized and characterized by elemental analysis and infrared spectroscopy (IR). Infrared spectroscopy data suggested that the nitrogen atom of the aromatic ring is bonded to the bismuth atom. The kinetic study of thermal degradation was determined by non-isothermal thermogravimetry. Two methods based on integral equation of Coats-Redfern, were necessary for determining the kinetic trip: the fitting method, known as the checking model and an iso-conversional method. The latter gives the activation energy for each degree of conversion and the first, the kinetic model gives activation energy and the pre-exponential factor for thermal decomposition processes that occur through a single simple mechanism. The kinetic parameters, E a and log A for the heating rates of 5, 10, and 15 min K −1 , were determined considering the decomposition model denoted by F0/R1 in the range of degree of conversion between 0.065 and 0.71.