Migration Reaction of a Silyl Group from a Phosphorus to a Carbonyl Oxygen in a Molybdenum Coordination Sphere
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS(2010)
Abstract
The reaction of Cp anion, [C5H4CH2CH2P(TMS)Mes](-) with (CH3CN)(3) Mo(CO)(3) leads to the formation of [(eta(5)-C5H4CH2CH2-P(TMS)Mes) MO(CO)(3)](-), which then reacts with MeI to give a metallaphosphacyclopropane complex with silyl migration.
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Key words
metallacycle,phosphine pendant,silyl migration
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