Synthesis and Reactivity of Bicyclic Phosphoric (and Thiophosphoric) Amides

Zhengjie He,Xavier M. Mbianda,Agnes M. Modro,Tom A. Modro,Susan Laurens

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS（2010）

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Abstract

This work summarizes studies on the preparation, structure, and reactivity of a new heterocyclic system containing phosphorus and nitrogen: 2,8-disubstituted-2,5,8-triaza-1lambda(5)-phosphabicyclo[3.3.0]octane 1-oxide (and 1-sulfide).

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Key words

bicyclic structures,lithiation-induced N double right arrow C phosphorus migration,N-phosphorylated nitrogen mustards,P-N bond cleavage

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