Unsaturated Carboxylic-Acid Dienolates - Addition To Substituted Cyclohexanones - Inverted Kinetic And Thermodynamic Stereoselectivities

TETRAHEDRON LETTERS(1987)

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摘要
Lithium dienolate of crotonic acid adds equatorially to cyclohexanones under kinetic conditions and axially or unselectively on equilibration.
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关键词
thermodynamics,kinetics
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