Fluorination of α,α-dichlorosulfides: access to gem-difluorothioethers as useful building blocks
Tetrahedron Letters(2003)
Abstract
The synthesis of alkylsulfanyldifluoro-acetate and ketones by the Halex reaction is described. The remarkable reactivity of thiodifluoroacetate derivatives opened rapid access for the preparation of useful building blocks such as gem-difluoroketones and amides.
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Key words
halogenation
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