The room temperature preparation of metastable fluorides and potent oxidizers

Journal of Fluorine Chemistry（2006）

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摘要

Because of the lower electronegativity of an oxidation state in an anion, AgF4− and NiF62− are made easily at room temperatures, with photo-activation of elemental F2, in basic aHF solutions. Electronegativity is higher in the metastable fluorides AgF3 and NiF4, and highest in cationic AgIII and NiIV species, which are yet, the most potent oxidizers.

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关键词

Electronegativity,High oxidation-states,Potent cationic oxidizers,Synthesis,AgF4−,NiF62− salts,Metastable fluorides,AgF3,NiF4,NiF3

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