The switch that wouldn't switch--unexpected luminescence from a ruthenium(II)-dppz-complex in water.

Matthias Schwalbe,Michael Karnahl,Stefanie Tschierlei,Ute Uhlemann,Michael Schmitt,Benjamin Dietzek,Jürgen Popp,Robert Groake,Johannes G Vos,Sven Rau

DALTON TRANSACTIONS（2010）

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摘要

The complex [(dmcb)(2)Ru(dppz)](PF6)(2) shows unexpected luminescence in water implying fundamentally different excited state relaxation pathways than are typically observed for complexes of this kind.

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