Efficient Nucleophilic Aromatic Substitution Between Aryl Nitrofluorides And Alkynes
ORGANIC LETTERS(2007)
Abstract
The nucleophilic aromatic substitution reaction between electron-deficient aryl fluorides and terminal alkynes is shown to be efficiently promoted by sodium bis(trimethylsilyl)amide as a base. Moderate to excellent yields of 2-ethynylnitrobenzene products can be obtained under mild conditions.
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