Synthesis of Phomopsin B

J. Grimley, A. Sawayama, H. Tanaka,M. Stohlmeyer, T. Woiwode, T. Wandless

Synfacts（2008）

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摘要

Phomopsin B is a potent microtubule-destabilizing agent, isolated from the fungus Phomopsis leptostromiformis. In the present synthesis fully functionalized building blocks are combined by peptide coupling reactions followed by a late-stage macrocyclization. Phomopsin B was obtained after 26 steps.

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synthesis

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