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First siloxane tethered paracyclophane

Journal of Organometallic Chemistry(2002)

引用 12|浏览5
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摘要
Treatment of 1,4-bis{[dimethyl(i-propoxy)silyl]vinyl}benzene (3) with water in the presence of base results in the formation of a siloxane tethered paradivnylbenzene cyclophane 2. The structure of 2 was confirmed by X-ray crystallography. UV and fluorescence spectra were measured and interaction between chromophores may occur.
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关键词
Paracyclophanes,Siloxane,UV spectrum,Fluorescence,X-ray structure
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