Synthesis Of Loliolide, Actinidiolide, Dihydroactinidiolide, And Aeginetolide Via Cerium Enolate Chemistry

JOURNAL OF ORGANIC CHEMISTRY（2006）

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摘要

Loliolide, aeginetolide, actinidiolide, and dihydroactinidiolide were synthesized in racemic form from a single common intermediate, prepared through the 1,2 addition of the cerium enolate of ethyl acetate to 2,6,6-trimethylcylohexenone.

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关键词

dihydroactinidiolide,loliolide,actinidiolide,cerium,aeginetolide

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