New fluorinated carbon support for catalysts

M.N Timofeeva,A.B Ayupov, V.N Mitkin, A.V Volodin,E.B Burgina,A.L Chuvilin,G.V Echevsky

Journal of Molecular Catalysis A-chemical（2004）

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摘要

The adsorption of H3PW12O40 from water and organic solvents by carbon meso-porous materials (Sibunit and fluorinated Sibunit (F-Sibunit)) was studied. A correlation between the rate constant of cyclohexene dimerisation of in the hexane solution and the strength of HPA-support interaction was determined.

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关键词

Heteropoly acid,Fluorinated carbon,Adsorption,Brønsted acidity,TEMPOL,Dimerisation of cyclohexene

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