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A new highly stereoselective construction of the sidechain of squalamine through improved Sharpless catalytic asymmetric dihydroxylation

Xiang-Dong Zhou,Feng Cai,Wei-Shan Zhou

Tetrahedron Letters（2001）

Cited 20|Views2
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Abstract
A new highly stereoselective construction of the sidechain of squalamine has been achieved by using methyl-3-keto-5α-chenodeoxycholanate (2) as the starting material and an improved Sharpless catalytic asymmetric dihydroxylation as the key step.
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Key words
methyl-5α-chenodeoxycholanate,desmosterol derivative,improved Sharpless AD,squalamine
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