聚丙烯酸叔丁酯的可控合成
Journal of Zhejiang Sci-Tech University(2010)
Abstract
以偶氮二异丁腈(AIBN)为引发剂,1-苯乙基二硫代苯乙酸酯(PEPDTA)为RAFT试剂,在乙酸乙酯中实施了丙烯酸叔丁酯(tBA)的RAFT自由基聚合.分子量测试表明,在高转化率(93%)下P(tBA)的分子量分布指数(Mw/Mn)小于1.1.且数均分子量与转化率成良好的线性关系,体现了可控/"活性"聚合的特征.
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Key words
reversible addition-fragmentation chain transfer(RAFT) radical polymerization,solution polymerization,tert-butyl acrylate
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